Hi Alfie
Intersting question.
In the earth’s atmosphere the pressure decreases as you go up and the atmosphere gets thinner. As air goes up it moves from higher to lower pressure and expands. As it expands it cools.
Hope that answers your question
At the top of a mountain the air is a lot thinner – the most air is closer to the ground. So as heat rises, it spreads out and cools down. At mountaintops it’s very cold because the air is so thin.
The sun also heats the earth on the ground, not the air. This means there is a lot more heat at ground level, even if it does start to rise up.
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